Can I use Monodevelop for projects created without Unity

I want to create a c# only project, but I don’t intend to use Unity.
I want to use resources like the .Net functions.
Can I do that with Unity’s Monodevelop?

Go to your mono develop (Find it where you installed Unity3d → Mono Develop(folder) ) , File → New → Solution … and choose your Target.
Done …