It is always best to install Visual Studio at the same time and in the same step as installing Unity.
This may help you with intellisense and possibly other Visual Studio integration problems:
Sometimes the fix is as simple as doing Assets → Open C# Project from Unity. Other times it requires more.
Other times it requires you also nuke the userprefs and .vsconfig and other crufty low-value high-hassle files that Visual Studio tends to slowly damage over time, then try the above trick.
Barring all that, move on to other ideas:
Also, try update the VSCode package inside of Unity: Window → Package Manager → Search for Visual Studio Code Editor → Press the Update button
Also, this: No suggestions in Vscode