For any class in System, Microsoft will have documentation on it. For any other class Unity provides, Unity will have documentation on it.
As a new developer, it’s also a good idea to just browse documentation like this for class names you’re becoming familiar with, just aimlessly and out of pure curiosity. It will speed your awareness and understanding of how everything fits together. It will give you new ideas on how to solve older problems better, or solve problems you haven’t had yet.
When documentation was in book form, I would keep a couple API manuals in my bathroom for light reading. Nowadays there’s smartphones and any API reference is at your fingertips.