The hotkeys in Visual Studio are customizable, so it’s usually better to look them up yourself.
Tools / Options / Environment / Keyboard
Some of the other ones I like, in no particular order:
Quick actions and refactoring suggestions (Most useful when your cursor is on top of red squiggles) (Default in VS 2015 and up: Ctrl + .)
Grep style file search (Default in VS 2015 and up: Ctrl + ,)
Intellisense (Default: Ctrl + Space Bar)
Available overloads (Only available when your cursor is inside the brackets of a method call) (Default: Ctrl + Shift + Space Bar)
Jump to definition (Default: F12)
Find all symbol references (Default: Ctrl K, R)
Rename symbol (Default: F2)
Jump to next error (Default: F8)
Format document with default VS style (very useful with xml docs or people as OCD about spaces as I am) (Default: Ctrl + K, D)
Toggle Breakpoint (Default: F9)
Remove all Breakpoints (Default: Ctrl + Shift + F9)
Start debugging (Default: F5)
Stop debugging (Default: Shift + F5)
Step in / Step over / Step up / Continue (Defaults: F11 / F10 / Shift + F11 / F5)
TestExplorer.Run/DebugAllTests (Defaults: Ctrl + R, A / Ctrl + R, Ctrl + A)
Run/Debug failing tests (No Default)
Run/Debug selected tests (No Default)
Jump to Solution Explorer (No Default)
Jump to Code (Default: F7)
Jump to Package Manager Console (Good for running any Powershell scripts) (No Default)
And here’s some other keyboard tricks:
Hold Ctrl while navigating your cursor with the left and right arrow keys to move word by word instead of character by character. This also works when selecting text with the Shift key
Hold Ctrl while navigating your cursor with the up and down arrow keys to scroll without losing your cursor’s place
Ctrl + Home is top of document, Ctrl + End is bottom
When Copy/Pasting code (looks over shoulder nervously … you didn’t hear it from me), select from the last character you want to copy UPWARDS to just after the last non-whitespace character you don’t want to copy. This usally means you are selecting some blank lines you wouldn’t normally select. Now you are in place to Ctrl + C, Ctrl + V, Ctrl + V. Yes, two Ctrl + V’s since the first will replace your current selection. It saves about 0.1 ms of repositioning your cursor