Wow, never seen that error before. I have no idea what it means.
Where do you see the error, is it a unity runtime error in the console, or is it in the result from your webserver?
Either way, you might want to look at this answer which lays out exactly how to send and receive data using www to a server, however it may not help if the error is coming from your web server.
describes something similar as a bug against the PHP version of Curl. It suggests that the problem is caused when using Digest authentication or following a server side re-direct. I suspect whatever is causing problems for PHP also causes problems for the WWWPost class. Guess Unity uses Curl also, but not on the iPhone. Note I am not saying that you have a PHP problem!
If you have any PHP coders there, perhaps hit your high score site using a PHP page and see if you get the same problem. I don't have a solution for you, but can only suggest you try without authentication to see if that is related.