95% of the time, you’ll use Transform.Rotate with only one of the slots filled in. for example, trans.rot(0, 5, 0) spins around y, like a top. trans.rot(0,0,5) spins around the forward axis, z, for windmill blades or something.
Using, for example, transform.Rotate(10,5,0) rotates 5 around y, then tilts 10 forwards around local x. That gives sort of a odd wobble, which you rarely want.
Transform.RotateAround is for those rare cases when you don’t want just a facing change (spin on Y) or lean (tilt on z) or tilt forwards (on x.) Say you are orbitting the center of a space station, using it’s facing to spin around. RotateAround could do that.
As far as the angles you’re getting with EulerAngle, they are semi-random. It stores the “real” angle using quaternions, and translates back when you ask.